MỤC LỤC
Từ các sơ đồ phản ứng sau (theo đúng tỉ lệ mol):
$\large \text{(1) 2}{{\text{X}}_{\text{1}}}\text{+ 2}{{\text{X}}_{\text{2}}}\text{ }\!\!~\!\!\text{ }\to \text{2}{{\text{X}}_{\text{3}}}\text{+ }{{\text{H}}_{\text{2}}}$
$\large \text{(2) }{{\text{X}}_{\text{3}}}\text{+ C}{{\text{O}}_{\text{2}}}\text{ }\!\!~\!\!\text{ }\!\!~\!\!\text{ }\to {{\text{X}}_{\text{4}}}$
$\large \text{(3)}\,{{\text{X}}_{\text{3}}}\text{+ }{{\text{X}}_{\text{4}}}\text{ }\!\!~\!\!\text{ }\to {{\text{X}}_{\text{5}}}\text{+ }{{\text{X}}_{\text{2}}}$
$\large \text{(4)}\,\text{2}{{\text{X}}_{\text{6}}}\text{+ 3}{{\text{X}}_{\text{5}}}\text{ }\!\!~\!\!\text{ + 3}{{\text{X}}_{\text{2}}}\to \text{2Fe}{{\left( \text{OH} \right)}_{\text{3}}}\text{+ 3C}{{\text{O}}_{\text{2}}}\text{+ 6KCl}$
Các chất thích hợp tương ứng với $\large {{\text{X}}_{\text{3}}}\text{, }{{\text{X}}_{\text{5}}}\text{, }{{\text{X}}_{\text{6}}}\text{ }\!\!~\!\!\text{ }$ lần lượt là
Lời giải chi tiết:
$\large {{X}_{1}}:K;\,{{X}_{2}}:{{H}_{2}}O;\,{{X}_{3}}:K\text{O}H$
$\large {{X}_{4}}:KHC{{O}_{3}};\,{{X}_{5}}:\,{{K}_{2}}C{{O}_{3}};\,{{X}_{6}}:\,F\text{e}C{{l}_{3}}$
$\large 2K+2{{H}_{2}}O\to 2K\text{O}H+{{H}_{2}}$
$\large K\text{O}H+C{{O}_{2}}\to KHC{{O}_{3}}$
$\large K\text{O}H+KHC{{O}_{3}}\to {{K}_{2}}C{{O}_{3}}+{{H}_{2}}O$
$\large 2F\text{e}C{{l}_{3}}+3{{K}_{2}}C{{O}_{3}}+3{{H}_{2}}O\to 2F\text{e}{{(OH)}_{3}}+3C{{O}_{2}}+6KCl$
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